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- W1609497567 abstract "An improved statistical theory of mass spectra is here applied to the fragmentation of five alkanes: n-hexane, 2-methylpentane, 3-methylpentane, n-heptane, and n-octane. The calculated breakdown curves are compared with the experimental curves obtained from photoionization studies by Steiner, Geise, and Inghram. The major fragmentations, the metastable ions, and the ``missing metastable'' ions are computed for gas temperatures of 0° and 300°K. The improved quasiequilibrium theory yields satisfactory breakdown curves for the above molecules using physically reasonable activated complexes and activation energies, and without requiring introduction of artificial parameters such as an ``effective number of oscillators.''" @default.
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- W1609497567 date "1966-09-15" @default.
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- W1609497567 title "Theoretical Calculations of Mass Spectra: Fragmentation of C<sub>6</sub>–C<sub>8</sub> Alkane Ions" @default.
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- W1609497567 doi "https://doi.org/10.1063/1.1727898" @default.
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