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- W161010662 abstract "Even though the spectra obtained by inductively coupled plasma source spectrometry (ICP-MS) are relatively simple, their interpretation can be complicated by the presence of molecular and isobaric interferants. To the extent that isotopic abundances are known and constant, one can treat observed spectra as sums of known components. A linear decomposition approach for determining the concentrations of the components in a spectrum and correctly propagating uncertainties is presented. This technique differs from linear regression in that an exact fit is made to a subset of isotopes and goodness-of-fit is evaluated from the deviations between the predicted and measured intensities of the other, unfit isotopes. This technique can be applied to a wide range of spectral fitting problems. In this paper, its applicability to ICP-MS spectra is used to demonstrate the use and utility of the technique. 2 refs., 9 figs." @default.
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- W161010662 date "1990-06-29" @default.
- W161010662 modified "2023-09-25" @default.
- W161010662 title "Reduction of multielement mass spectra" @default.
- W161010662 doi "https://doi.org/10.2172/6441133" @default.
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