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- W1610148450 abstract "state. Therefore, upper vibrational levels (v 0 ‚ 3) of the A 1 ƒ state cannot be determined by means of the equilibrium constants calculated in the previous works. Due to so far unidentifled A 1 ƒ state perturbations, the reduction of the wave numbers to the rovibronic parameters was carried out by means of individual, band-by-band analysis method, using with this end in view the nonlinear least squares method introduced by Curl and Dane, and Watson. This method allowed one to make already calculated constants of the rovibronic structure of regular lower state X 1 § + of AiX system independent of possible perturbations appearing in the upper state of A 1 ƒ of this system. It also enabled one to calculate for the flrst time the real (perturbed) term values for the A 1 ƒ (v 0 = 0, 1, 2, and 3) state of the 12 CH + ion molecule. These values suggest that rotational irregularities in the A 1 ƒ state examined are negligibly small. In order to conflrm the nonexistence of rotational perturbations in the A 1 ƒ (v 0 = 0, 1, 2, and 3) state, up to the observed Jmax ¶" @default.
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- W1610148450 date "2007-06-01" @default.
- W1610148450 modified "2023-10-17" @default.
- W1610148450 title "Analysis of the A<sup>1</sup>Π State on the Basis of the Douglas-Herzberg Bands System in the CH+ Ion Molecule" @default.
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- W1610148450 doi "https://doi.org/10.12693/aphyspola.111.821" @default.
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