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- W1610532093 abstract "<TEX>$[Mn_{12}O_{12}(O_2CPh-4-SMe)_{16}(H_2O)_4]{cdot}7CH_2Cl_2$</TEX> (1), a new single-molecule magnet complex has been successfully synthesized by substitution of acetate ligand of Mn12ac with 4-(methylthio)benzoic acid. Complex 1 crystallizes into triclinic P<TEX>$overline{1}$</TEX> with a = 18.321(3) <TEX>$AA$</TEX>, b = 19.011(3) <TEX>$AA$</TEX>, c = 27.230(4) <TEX>$AA$</TEX>, <TEX>$alpha$</TEX> = 86.973(3)<TEX>$^{circ}$</TEX>, <TEX>$beta$</TEX> = 76.919(3)<TEX>$^{circ}$</TEX>, <TEX>$gamma$</TEX> = 87.613(3)<TEX>$^{circ}$</TEX>, and Z = 2. In complex 1, one Mn(III) ion has an abnormal Jahn-Teller elongation axis oriented at an oxide ion. Complex 1 has two out-of-phase ac susceptibility peaks in the 2-4 K and 4-7 K regions. Effective anisotropy energy barrier and pre-exponential factor are <TEX>$U_{eff}$</TEX> = 45.95 K, 1/<TEX>$tau$</TEX>0 = 8.6 <TEX>${times};10^9s^{-1};for;{chi}_M$</TEX>'' peaks in the lower temperature region and <TEX>$U_{eff}$</TEX> = 59.45 K, 1/<TEX>$tau_0$</TEX> = 2.2 <TEX>${times};10^8;s^{-1}$</TEX> for <TEX>$chi_M$</TEX>'' peaks in the higher temperature region. The parameters of S = 10, g = 1.87, D = -0.40 <TEX>$cm^{-1}$</TEX>, and E = 0.00034 <TEX>$cm^{-1}$</TEX> were obtained from the M/N<TEX>${mu}_B$</TEX> vs. H/T plot of complex 1." @default.
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- W1610532093 date "2005-07-20" @default.
- W1610532093 modified "2023-10-18" @default.
- W1610532093 title "Synthesis, Structure and Magnetic Properties of Mn12Single Molecule Magnet Containing 4-(Methylthio)benzoate as Peripheral Ligands" @default.
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- W1610532093 doi "https://doi.org/10.5012/bkcs.2005.26.7.1065" @default.
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