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- W1611593337 abstract "The B 6Π–X 6Σ+ band system of the CrF radical has been recorded in emission with FTS techniques in the region between 6965 and 9240 cm−1, using a resolution of 0.025 cm−1. A rotational analysis including the (0,0), (1,1), (1,0), (0,1) and (1,2) bands of this system has been carried out, and a set of molecular parameters has been derived for the B 6Π state. The present analysis has also resulted in substantially better determined values for the λ and γ parameters of the X 6Σ+ ground state. An improved set of molecular parameters has been derived for the previously analyzed, heavily perturbed A 6Σ+ state. The present analysis gives strong support for the interpretation that the local perturbations in the v=0–3 levels of A 6Σ+ are due to interactions with the vibrational levels v=3–6 of the B 6Π state. Earlier suggestions involving a low-lying 4Π state as the dominating perturber of the A 6Σ+ state must now be considered as erroneous. A previously suggested interpretation of the 7400 cm−1 band as being possibly due to a quartet transition has also been shown to be in error. The derived first order spin-orbit parameter value of B 6Π [A=47.0382(18) cm−1] and the equilibrium bond distances of X 6Σ+ [1.7839 Å], A 6Σ+ [1.8919 Å], and B 6Π [1.8277 Å] have been discussed, and it has been proposed that the 9σ (Cr4s–4p) molecular orbital of CrF is slightly bonding, while 4π (Cr3dπ) is nonbonding and 10σ (Cr3dσ) antibonding." @default.
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- W1611593337 date "1996-07-08" @default.
- W1611593337 modified "2023-09-23" @default.
- W1611593337 title "Spectroscopy of CrF: Rotational analysis of the B 6Π–X 6Σ+ band system in the 1.2 μm region" @default.
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- W1611593337 doi "https://doi.org/10.1063/1.471915" @default.
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