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- W1612528357 abstract "We report measurements and analyses of resistivity, thermopower and thermal conductivity of polycrystalline samples of perovskite LaRh(1-x)Ni(x)O(3). The thermopower is found to be large at 800 K (185 µV K(-1) for x = 0.3), which is ascribed to the high-temperature stability of the low-spin state of Rh(3+)/Rh(4+) ions. This clearly contrasts with the thermopower of the isostructural oxide LaCoO(3), which rapidly decreases above 500 K owing to the spin-state transition. The spin state of the transition-metal ions is one of the most important parameters in oxide thermoelectrics." @default.
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- W1612528357 date "2009-02-17" @default.
- W1612528357 modified "2023-10-13" @default.
- W1612528357 title "Thermoelectric properties of LaRh<sub>1−<i>x</i></sub>Ni<sub><i>x</i></sub>O<sub>3</sub>" @default.
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- W1612528357 doi "https://doi.org/10.1088/0953-8984/21/11/115501" @default.
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