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- W161308485 abstract "The phase separation of suspensions of anisotropic rod-like species such as tobacco mosaic virus, DNA fragments and collagen into fluids displaying nematic or chiral nematic order is a widely observed phenomenon. Suspensions of rod-like cellulose crystallites also can form a chiral nematic phase. The rodlets of crystalline cellulose were prepared by sulphuric acid hydrolysis of natural cellulose fibres from several sources. The suspensions are thought to be stabilized by the charged sulphate ester groups on the surface of the crystallites. Well-formed textures and disclinations characteristic of chiral nematic liquid crystals, readily formed by these dilute suspensions, are observed. Preliminary results indicate that the critical volume fraction for phase separation of salt-free suspensions can be as low as 0.03, with a relatively narrow biphasic region. The phase separation is sensitive to the ionic strength of the medium. Some effects of magnetic fields on the orientation of the ordered phase will also be described." @default.
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- W161308485 date "1995-01-01" @default.
- W161308485 modified "2023-09-27" @default.
- W161308485 title "Chiral nematic suspensions of cellulose" @default.
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- W161308485 doi "https://doi.org/10.1533/9781845698539.5.371" @default.
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