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• W1613538541 endingPage "1865" @default.
• W1613538541 startingPage "1865" @default.
• W1613538541 abstract "An increment of electron paramagnetic absorption was observed in a dimethylformamide (DMF) solution of polyvinylidenefluoride (PVDF) in which C 60 was ultrasonically dispersed. A polymer film containing paramagnetic C 60 was obtained by vacuum evaporation of the solvent DMF, and the film, which was free from metallic contaminations, exhibited ferromagnetic characteristics even at ambient temperatures. A transmission electron microscope (TEM) observation on thin slices of the sample film showed rod-shaped aggregates of fine crystalline C 60 with cross sections of 2–8 µ m which were regularly arrayed and aligned in a certain direction. By laser desorption ionization time-of-flight mass spectroscopy (LDITOF-MS) on the samples, C 60 adducts with R (R=H, F, CF 3 and polymer fragments) were detected, which seemed to be formed as C 60 radical adducts immediately after scission of the polymer chain by sonication. The observed magnetism seems to be carried out by the radical adducts represented as C 60 R n , where n is odd." @default.
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• W1613538541 date "1994-04-01" @default.
• W1613538541 modified "2023-10-16" @default.
• W1613538541 title "Polymer-C₆₀ Composite with Ferromagnetism" @default.
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• W1613538541 doi "https://doi.org/10.1143/jjap.33.1865" @default.
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