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- W1614247437 abstract "H-atom channels in the photodissociation of jet-cooled ethyl radical (C2H5) via the à 2A′(3s) state are studied near 245 nm by using the high-n Rydberg-atom time-of-flight technique. Bimodal product translational energy release and energy-dependent angular distribution suggest two dissociation pathways. A slow (〈fT〉∼0.35) and isotropic channel corresponds to unimolecular dissociation of the radical, presumably after internal conversion. A previously unobserved fast (〈fT〉∼0.78) and anisotropic (β=0.5±0.1) channel is consistent with direct H-atom scission via a nonclassical H-bridged transition state from the 3s state to yield H+C2H4(X̃ 1Ag). The fast/slow branching ratio is ∼0.2. Site-selective loss of the β hydrogen atom is confirmed by using the partially-deuterated CH3CD2 radical." @default.
- W1614247437 created "2016-06-24" @default.
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- W1614247437 date "2001-03-22" @default.
- W1614247437 modified "2023-10-03" @default.
- W1614247437 title "UV photodissociation dynamics of ethyl radical via the à 2A′(3s) state" @default.
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- W1614247437 doi "https://doi.org/10.1063/1.1350936" @default.
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