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• W1615501246 abstract "Amorphous arsenic sulphide (As2S3) films prepared by ultrafast pulsed laser deposition have been vacuum annealed at a range of different temperatures. Measurements of the glass transition temperature indicate that a crystallization process initiates at annealing temperatures around 170°C. In combination with Raman scattering analysis, we conclude that phase separation is intrinsic for our as-deposited films. During annealing two sorts of phase transformation are identified: one between different amorphous polymorphs, and another from the amorphous to a crystalline state. We point out a correlation between these two types of transformation and two characteristic time scales identified from measurements of the relaxation of the refractive index, and explain the Arrhenius and non-Arrhenius behaviors leading to the observed temporal characteristics." @default.
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• W1615501246 date "2006-09-15" @default.
• W1615501246 modified "2023-10-15" @default.
• W1615501246 title "Annealing induced phase transformations in amorphous As2S3 films" @default.
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• W1615501246 doi "https://doi.org/10.1063/1.2353787" @default.
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