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• W1617451103 abstract "Abstract The functional self‐organization can be transcribed readily into hybrid nanostructures by using the sol‐gel process. Accordingly, we have reported synthetic routes for preparing self‐organized systems that have been “frozen” in a siloxane matrix, as a straightforward approach to design a novel class of solid hybrid nanomaterials. Nucleobases oligomerization can be an advantageous choice to reinforce the controlled communication between interconnected “dynamic supramolecular” and “fixing siloxane” systems. Moreover, the different interconverting outputs that nucleobases may form by oligomerization define a dynamic polyfunctional diversity that may be “extracted selectively” by sol‐gel polymerization in solid state under the intrinsic stability of the different nucleobase‐pairing and G‐quadruplex‐based systems. The nucleobase‐type hybrid materials presented in this review unlock the door to the new self‐organized materials world paralleling that of biology." @default.
• W1617451103 created "2016-06-24" @default.
• W1617451103 creator A5067547000 @default.
• W1617451103 date "2008-05-15" @default.
• W1617451103 modified "2023-10-10" @default.
• W1617451103 title "Nucleobase Self‐Assembly Codes: Constitutional Transcription" @default.
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• W1617451103 doi "https://doi.org/10.1002/9780470048672.wecb527" @default.
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