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• W1619208934 abstract "The effect of Ti substitution by Sc on the thermoelectric properties of the Heusler compounds NiTi0.3−xScxZr0.35Hf0.35Sn (where 0&lt;x≤0.05) was studied. The thermoelectric properties were investigated by measuring the electrical conductivity, Seebeck coefficient, and thermal conductivity. A reduction of the thermal conductivity by a factor of 2 was obtained by substitution of Ti by Sc. The pure compound NiTi0.3Zr0.35Hf0.35Sn showed n-type conductivity with a Seebeck coefficient of −288 μV/K at 350 K, while under Sc substitution the system switched to p-type behavior. A maximum Seebeck coefficient of +230 μV/K (350 K) was obtained by 4% Sc substitution, which is the highest value for p-type thermoelectric compounds based on Heusler alloys. The electronic structure was studied by photoelectron spectroscopy excited by hard x-ray synchrotron radiation. Massive in gap states are observed for the parent compound. This proves that the electronic states close to the Fermi energy play a key role on the behavior of the transport properties. Especially, they are responsible for the high, negative Seebeck coefficient of the parent compound." @default.
• W1619208934 created "2016-06-24" @default.
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• W1619208934 date "2010-12-20" @default.
• W1619208934 modified "2023-10-02" @default.
• W1619208934 title "Thermoelectric properties and electronic structure of substituted Heusler compounds: NiTi0.3−xScxZr0.35Hf0.35Sn" @default.
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• W1619208934 doi "https://doi.org/10.1063/1.3531662" @default.
• W1619208934 hasPublicationYear "2010" @default.
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