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• W1620033730 abstract "The polycrystalline samples of ferrimagnetic FeCr2−xMxS4 (M=In,Al; x=0.1,0.3) have been studied with x-ray diffraction, magnetization, and Mössbauer spectroscopy measurements. The crystal structure was found to be cubic spinel with Fd-3m space group. The lattice constants (a0) of the samples were linearly increased with Al and In concentration. Mössbauer spectra of FeCr2−xMxS4 (M=In,Al; x=0.1,0.3) were obtained at various temperatures ranging from 4.2 to 300 K. Magnetic hyperfine field and electric quadrupole interactions for FeCr2−xMxS4 (M=In,Al; x=0.1) at 4.2 K have been fitted, yielding the following results: for M=Al, Hhf=139 kOe, ΔEQ=2.54 mm/s, θ=30°, φ=0.0°, η=0.9, and R=2.7; and for M=In, Hhf=126 kOe, ΔEQ=2.64 mm/s, θ=30°, φ=0.0°, η=1.0, and R=3.1. The isomer shift (δ) value of the FeCr2−xMxS4 (x=0.1) samples for both M=Al and In at 300 K was 0.50 mm/s, relative to the Fe metal, which is consistent with the Fe2+ valence state. The Debye temperatures (ΘD) of the FeCr2−xAlxS4 (x=0.1,0.3) sample were determined to be 299±5 and 247±5 K, respectively, and those of the FeCr2−xInxS4 (x=0.1,0.3) samples were determined to be 257±5 and 239±5 K, respectively." @default.
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• W1620033730 date "2010-04-15" @default.
• W1620033730 modified "2023-09-26" @default.
• W1620033730 title "Magnetic properties of the ferrimagnetic FeCr2−xMxS4 (M=In,Al)" @default.
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• W1620033730 doi "https://doi.org/10.1063/1.3337662" @default.
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