Matches in SemOpenAlex for { <https://semopenalex.org/work/W1621052967> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W1621052967 endingPage "48" @default.
- W1621052967 startingPage "39" @default.
- W1621052967 abstract "Reaction of bis-(acetylacetonato) copper(ΙΙ) (A) with transmetalator Zn((EtO)2PS2)2 (B2; Et = ethyl) in methylene chloride is a simple irreversible second-order process over a wide temperature range which is the first example of a second-order reaction of mononuclear target A with a transmetalator. The plots of kobsd vs [A] are linear, meaning that there is one A and one B2 in the activated complex of the slowest reaction step. The slowest step is precursor formation on the basis that B2 is an exceptionally weak complex. The product of the A/B2 reaction is the strong successor complex Zn(acac)2•Cu(ps)2. The data are compared with those for reactions of the same target (A) with S-methyle isopropylidenehydrazinecarbodithioate-carbodithioato-metal(II) complexes M(SN)2 (M=Ni (C1) and Zn (C2)). The reaction is not like that of A with Ni ((MeO)2PS2)2 (B1; Me=methyl), because it is irreversible and also consistent with the measured lower relative thermodynamic stability of B2 compared to B1." @default.
- W1621052967 created "2016-06-24" @default.
- W1621052967 creator A5022897316 @default.
- W1621052967 date "2015-01-01" @default.
- W1621052967 modified "2023-10-16" @default.
- W1621052967 title "Products and Kinetics of the Reaction of Monomeric Target Bis-(Acetylacetonato) Copper(II) with Transmetalator Bis-(Diethoxydithiophosphato) Zinc(II) in Methylene Chloride" @default.
- W1621052967 cites W1966224046 @default.
- W1621052967 cites W1971212467 @default.
- W1621052967 cites W1973416735 @default.
- W1621052967 cites W1998400242 @default.
- W1621052967 cites W2001199512 @default.
- W1621052967 cites W2002220072 @default.
- W1621052967 cites W2008746115 @default.
- W1621052967 cites W2010822185 @default.
- W1621052967 cites W2012090532 @default.
- W1621052967 cites W2014673471 @default.
- W1621052967 cites W2025433008 @default.
- W1621052967 cites W2032630526 @default.
- W1621052967 cites W2033025701 @default.
- W1621052967 cites W2035411481 @default.
- W1621052967 cites W2037717719 @default.
- W1621052967 cites W2042939917 @default.
- W1621052967 cites W2047014528 @default.
- W1621052967 cites W2049101014 @default.
- W1621052967 cites W2052247457 @default.
- W1621052967 cites W2058588111 @default.
- W1621052967 cites W2062585575 @default.
- W1621052967 cites W2065057000 @default.
- W1621052967 cites W2071857464 @default.
- W1621052967 cites W2073676832 @default.
- W1621052967 cites W2075113406 @default.
- W1621052967 cites W2377212612 @default.
- W1621052967 cites W2604699882 @default.
- W1621052967 cites W3138962115 @default.
- W1621052967 cites W327091490 @default.
- W1621052967 doi "https://doi.org/10.4236/ojpc.2015.52005" @default.
- W1621052967 hasPublicationYear "2015" @default.
- W1621052967 type Work @default.
- W1621052967 sameAs 1621052967 @default.
- W1621052967 citedByCount "0" @default.
- W1621052967 crossrefType "journal-article" @default.
- W1621052967 hasAuthorship W1621052967A5022897316 @default.
- W1621052967 hasBestOaLocation W16210529671 @default.
- W1621052967 hasConcept C121332964 @default.
- W1621052967 hasConcept C135502975 @default.
- W1621052967 hasConcept C148898269 @default.
- W1621052967 hasConcept C155647269 @default.
- W1621052967 hasConcept C161790260 @default.
- W1621052967 hasConcept C175113610 @default.
- W1621052967 hasConcept C178790620 @default.
- W1621052967 hasConcept C179104552 @default.
- W1621052967 hasConcept C185592680 @default.
- W1621052967 hasConcept C2777454769 @default.
- W1621052967 hasConcept C2778695967 @default.
- W1621052967 hasConcept C535196362 @default.
- W1621052967 hasConcept C544778455 @default.
- W1621052967 hasConcept C62520636 @default.
- W1621052967 hasConcept C93391505 @default.
- W1621052967 hasConceptScore W1621052967C121332964 @default.
- W1621052967 hasConceptScore W1621052967C135502975 @default.
- W1621052967 hasConceptScore W1621052967C148898269 @default.
- W1621052967 hasConceptScore W1621052967C155647269 @default.
- W1621052967 hasConceptScore W1621052967C161790260 @default.
- W1621052967 hasConceptScore W1621052967C175113610 @default.
- W1621052967 hasConceptScore W1621052967C178790620 @default.
- W1621052967 hasConceptScore W1621052967C179104552 @default.
- W1621052967 hasConceptScore W1621052967C185592680 @default.
- W1621052967 hasConceptScore W1621052967C2777454769 @default.
- W1621052967 hasConceptScore W1621052967C2778695967 @default.
- W1621052967 hasConceptScore W1621052967C535196362 @default.
- W1621052967 hasConceptScore W1621052967C544778455 @default.
- W1621052967 hasConceptScore W1621052967C62520636 @default.
- W1621052967 hasConceptScore W1621052967C93391505 @default.
- W1621052967 hasIssue "02" @default.
- W1621052967 hasLocation W16210529671 @default.
- W1621052967 hasOpenAccess W1621052967 @default.
- W1621052967 hasPrimaryLocation W16210529671 @default.
- W1621052967 hasRelatedWork W1637416466 @default.
- W1621052967 hasRelatedWork W1980902636 @default.
- W1621052967 hasRelatedWork W1988575503 @default.
- W1621052967 hasRelatedWork W2001071190 @default.
- W1621052967 hasRelatedWork W2028747097 @default.
- W1621052967 hasRelatedWork W2059666662 @default.
- W1621052967 hasRelatedWork W2358229883 @default.
- W1621052967 hasRelatedWork W2359981949 @default.
- W1621052967 hasRelatedWork W2510253675 @default.
- W1621052967 hasRelatedWork W610031948 @default.
- W1621052967 hasVolume "05" @default.
- W1621052967 isParatext "false" @default.
- W1621052967 isRetracted "false" @default.
- W1621052967 magId "1621052967" @default.
- W1621052967 workType "article" @default.