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- W1621931474 abstract "The interaction of low energy electrons with acetate adsorbed on the (110) surfaces of rutile TiO2 has been studied using electron stimulated desorption ion angular distribution, low energy electron diffraction and scanning tunnelling microscopy. The adsorption of acetic acid at room temperature is dissociative, and produces a layer of carboxylate species and surface hydroxyl species in an ordered array. Irradiation of the adsorbate covered TiO2(110) surface causes the dissociation of the surface species, leading to the desorption of a range of charged particles. The dominant desorption products are the H+ ions. The H+ ESD ion angular distribution can be resolved into two contributions: those ions desorbed from hydrogen atoms bonded at the oxide substrate, and those desorbed via the rupture of the C-H bonds of the acetate species. The geometry of the ESDIAD pattern led us to propose that the carboxylate species is bound to the Ti4+ ions with the molecular axis perpendicular to the surface." @default.
- W1621931474 created "2016-06-24" @default.
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- W1621931474 date "2000-01-01" @default.
- W1621931474 modified "2023-09-25" @default.
- W1621931474 title "Electron stimulated desorption of charged particles from acetate covered rutile TiO[sub 2](110)" @default.
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- W1621931474 doi "https://doi.org/10.1063/1.1303799" @default.
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