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- W1622452011 abstract "We present $^{13}mathrm{C}$ NMR experiments performed on pure ${mathrm{C}}_{60}$ crystalline powders. High resolution in the solid state on a very pure sample allows us to measure an extremely narrow (1.8-Hz linewidth) resonance at 143.6 ppm characteristic of the rotating molecule. The intercalation of ${mathrm{O}}_{2}$ molecules in the fcc structure induces an additional resonance (at 144.3 ppm) whose intensity is directly related to the oxygen content. At room temperature the ${mathrm{O}}_{2}$ intercalation is partially reversible. By analysis of the $^{13}mathrm{C}$ resonance shape of this additional resonance we characterize the hindrance in the ${mathrm{C}}_{60}$ rotation introduced by the intercalated species." @default.
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- W1622452011 date "1993-06-15" @default.
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- W1622452011 title "Intercalation of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>in solid<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>C</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and molecular-rotation…" @default.
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- W1622452011 doi "https://doi.org/10.1103/physrevb.47.15980" @default.
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