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• W1622753612 abstract "The first overtones of some OH and NH stretching vibrations affected by strong hydrogen bonding were measured. The anharmonicity shows a net increase with respect to the related “free” OH and NH vibrations. A general discussion based on the data of the present paper and two previous papers from this laboratory is presented. It is shown that conventional second-order perturbation theory is inadequate in dealing with the anharmonicity of vibrations influenced by hydrogen bonds. Better results are obtained when the off-diagonal terms of the quartic potential constant are included. The posssible effect of higher terms is qualitatively discussed and the relation between anharmonicity and the frequency shift caused by hydrogen bonding is examined. It is concluded that hydrogen bonding has a profound effect on anharmonicity." @default.
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• W1622753612 date "1966-07-01" @default.
• W1622753612 modified "2023-10-16" @default.
• W1622753612 title "Anharmonicity and hydrogen bonding" @default.
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• W1622753612 doi "https://doi.org/10.1016/0022-2852(66)90029-4" @default.
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