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- W1623408832 abstract "A series of molybdenum disulfide intercalation compounds was prepared to study the effect of varying loadings of the samples with intercalated molecules. The molecules, (5,7,7,12,14,14-hexamethyl-1,4,8,11- tetraazacyclotetradeca-4,11-diene) macrocycles, occupy the gallery spaces between the MoS2 layers in a single layer. The samples were characterized by thermogravimetry, wide angle X-ray scattering, scanning electron microscopy and transmission electron microscopy (TEM). TEM images reveal the layer stacking as the filling of the gallery spaces with macrocycles increases gradually up to one monolayer per gallery space. Fourier transforms of these images are in excellent agreement with the X-ray scattering of the bulk compound. X-ray scattering by these compounds was simulated by evaluating the Debye sum for weighted averages of model particles that have sequences of open and closed gallery spaces. Open and closed gallery spaces coexist in the samples with less than one monolayer of intercalated molecules per gallery space. The fraction of open gallery spaces increases with macrocycle loading, from zero for restacked MoS2 without macrocycles to one for a fully intercalated compound. The sequence of open and closed spaces is approximately random, and the MoS2 layers stack with the same orientation but with random lateral shifts. The binding enthalpy of the macrocycles in the gallery spaces is about 14 meV." @default.
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- W1623408832 date "2006-07-05" @default.
- W1623408832 modified "2023-09-27" @default.
- W1623408832 title "Coexistence of open and closed gallery spaces in intercalation compounds" @default.
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