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- W1623960843 abstract "Publisher Summary Metal carbonyls, which were among the earliest discovered organometallic compounds, continue to play a central role in organometallic chemistry. Carbonyl basicity is found for C-bridging CO ligands in metal–metal bonded compounds, CO ligands in anionic metal carbonyls, or CO ligands in donor-substituted metal carbonyls. The interaction of protons with mononuclear metal carbonyls readily occurs at the metal center rather than the CO oxygen; no stable or transient MCO–H species appear to have been observed. The chemical and structural characterization of molecular compounds containing π–CO is of great interest, because the π–CO is implicated as a precursor to the cleavage of CO on metal surfaces, such as those employed in Fischer–Tropsch catalysis. In view of these large physical changes, it perhaps is not surprising that C and O bonding also engenders large changes in CO reactivity. Carbon monoxide insertion into a metal–alkyl bond is a fundamental reaction in organometallic chemistry as well as an important step in the commercial production of oxygen-containing organics, such as aldehydes and acetic acid." @default.
- W1623960843 created "2016-06-24" @default.
- W1623960843 creator A5049010735 @default.
- W1623960843 creator A5066827799 @default.
- W1623960843 date "1984-01-01" @default.
- W1623960843 modified "2023-10-16" @default.
- W1623960843 title "C- and O-Bonded Metal Carbonyls: Formation, Structures, and Reactions" @default.
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