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- W1624188125 abstract "This chapter discusses the probable mechanisms involved in biological phosphoryl transfer reactions as disclosed by the studies of model systems and their extrapolation to the enzyme mediated processes. Various lines of evidence have led to a general acceptance of the dissociative monomeric metaphosphate mechanism for the hydrolysis of monoester monoanions derived from alcohols and phenols, thiols, and amines. The principal supporting data include: (a) a general observation of P–O, P–S, or P–N bond cleavage; (b) entropies of activation close to zero in contrast to bimolecular or associative solvolyzes where entropies of activation are usually more negative by 20 eu; (c) molar product compositions (methyl phosphate : inorganic phosphate) in mixed methanol–water solvent that approximate the molar ratio of methanol, water or favor methyl phosphate formation, inferring the presence of a highly reactive electrophilic species; and (d) the existence of linear free-energy relationships between the logarithmic rates of hydrolysis of the monoanions and the dissociation constants of the corresponding leaving group. This chapter describes the hydrolysis of acyclic phosphate esters. Nucleophilic reactions at acyclic phosphorus are discussed in the chapter. Catalysis of phosphoryl transfer or ligand loss is also discussed in the chapter." @default.
- W1624188125 created "2016-06-24" @default.
- W1624188125 creator A5057047461 @default.
- W1624188125 creator A5057578570 @default.
- W1624188125 date "1973-01-01" @default.
- W1624188125 modified "2023-10-14" @default.
- W1624188125 title "6 Chemical Basis of Biological Phosphoryl Transfer" @default.
- W1624188125 cites W1122424616 @default.
- W1624188125 cites W1431369838 @default.
- W1624188125 cites W1479846693 @default.
- W1624188125 cites W155146360 @default.
- W1624188125 cites W1592881773 @default.
- W1624188125 cites W1833684078 @default.
- W1624188125 cites W1867672953 @default.
- W1624188125 cites W1965180617 @default.
- W1624188125 cites W1967018847 @default.
- W1624188125 cites W1968733176 @default.
- W1624188125 cites W1974903485 @default.
- W1624188125 cites W1982922463 @default.
- W1624188125 cites W1983827372 @default.
- W1624188125 cites W1985684677 @default.
- W1624188125 cites W1988623356 @default.
- W1624188125 cites W1990881352 @default.
- W1624188125 cites W1991612170 @default.
- W1624188125 cites W2000366586 @default.
- W1624188125 cites W2001269243 @default.
- W1624188125 cites W2005148229 @default.
- W1624188125 cites W2006913439 @default.
- W1624188125 cites W2013547365 @default.
- W1624188125 cites W2013987631 @default.
- W1624188125 cites W2017901238 @default.
- W1624188125 cites W2018234647 @default.
- W1624188125 cites W2019237634 @default.
- W1624188125 cites W2022774390 @default.
- W1624188125 cites W2024538943 @default.
- W1624188125 cites W2026070583 @default.
- W1624188125 cites W2027298627 @default.
- W1624188125 cites W2028162013 @default.
- W1624188125 cites W2029131049 @default.
- W1624188125 cites W2032545978 @default.
- W1624188125 cites W2039750430 @default.
- W1624188125 cites W2040263894 @default.
- W1624188125 cites W2042373281 @default.
- W1624188125 cites W2043782234 @default.
- W1624188125 cites W2045686669 @default.
- W1624188125 cites W2049419263 @default.
- W1624188125 cites W2051453433 @default.
- W1624188125 cites W2051678814 @default.
- W1624188125 cites W2053952223 @default.
- W1624188125 cites W2060593434 @default.
- W1624188125 cites W2065302372 @default.
- W1624188125 cites W2066219821 @default.
- W1624188125 cites W2066872027 @default.
- W1624188125 cites W2068276440 @default.
- W1624188125 cites W20751628 @default.
- W1624188125 cites W2078232028 @default.
- W1624188125 cites W2079167403 @default.
- W1624188125 cites W2083872895 @default.
- W1624188125 cites W2084359523 @default.
- W1624188125 cites W2084901235 @default.
- W1624188125 cites W2086765626 @default.
- W1624188125 cites W2087732491 @default.
- W1624188125 cites W2089190165 @default.
- W1624188125 cites W2094683945 @default.
- W1624188125 cites W2140210892 @default.
- W1624188125 cites W2170686947 @default.
- W1624188125 cites W2212142497 @default.
- W1624188125 cites W2312368595 @default.
- W1624188125 cites W2312674561 @default.
- W1624188125 cites W2313795744 @default.
- W1624188125 cites W2313986148 @default.
- W1624188125 cites W2314168444 @default.
- W1624188125 cites W2314516278 @default.
- W1624188125 cites W2317935115 @default.
- W1624188125 cites W2318160754 @default.
- W1624188125 cites W2318259478 @default.
- W1624188125 cites W2318358038 @default.
- W1624188125 cites W2319032073 @default.
- W1624188125 cites W2319336768 @default.
- W1624188125 cites W2319977830 @default.
- W1624188125 cites W2320806206 @default.
- W1624188125 cites W2322818186 @default.
- W1624188125 cites W2323541475 @default.
- W1624188125 cites W2324693368 @default.
- W1624188125 cites W2326293502 @default.
- W1624188125 cites W2327652556 @default.
- W1624188125 cites W2327909803 @default.
- W1624188125 cites W2328392914 @default.
- W1624188125 cites W2331377560 @default.
- W1624188125 cites W2334023232 @default.
- W1624188125 cites W2335779671 @default.
- W1624188125 cites W2402786253 @default.
- W1624188125 cites W2467870672 @default.
- W1624188125 cites W2526723170 @default.
- W1624188125 cites W4211160628 @default.
- W1624188125 cites W4235021825 @default.
- W1624188125 cites W4247605785 @default.
- W1624188125 cites W4296843051 @default.