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- W1624808520 abstract "Abstract The keto ⇋ enol equilibrium of pentane-2,4-dione (PD) has been measured in 21 solvents at infinite dilution and a linear free energy relationship (LFER) tested against four solvent polarity vectors: ϵ, ET, π* and A + B. The best correlation coefficient is found for A + B. Similarly 3-methyl-pentane-2,4-dione (MePD) has been studied in 14 solvents and 3-ethylpentane-2,4-dione (EtPD) in six. The results suggest that the cyclic hydrogen bonding of the enol remains intact in all the solvents studied." @default.
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- W1624808520 date "1987-10-01" @default.
- W1624808520 modified "2023-09-25" @default.
- W1624808520 title "β-diketone interactions" @default.
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- W1624808520 doi "https://doi.org/10.1016/0022-2860(87)85074-3" @default.
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