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- W1626001215 abstract "Abstract Abstract. The title compounds NH 4 [Cu(S 2 CNH 2 ) 2 ] · H 2 O (A) and CuS 2 CNH 2 (B) were prepared from aqueous alcoholic solutions by reaction of ammoniumdithiocarbamate with copper sulfate in presence of excess cyanide as reductive. (A) crystallizes in the orthorhombic space group C 222 1 (No. 20) with a = 8.9518(6), b = 9.6414(6) and c = 10.6176(8) Å, Z = 4. (B) crystallizes in the orthorhombic space group P 2 1 2 1 2 1 (No. 19) with a = 5.9533(4), b = 6.6276(4) and c = 9.4834(5) Å, Z = 4. In the crystal structure of (A) copper has a tetrahedral surrounding of four monodentate dithiocarbamate ligands. These structural units form 2D nets stacked along [001]. Staggered chains consisting of H 2 O and NH 4 + penetrate the crystal structure along [001] yielding additional coherence via hydrogen bonds. The crystal structure of (B) comprises a three‐dimensional tetrahedral framework of CuS 4 units exclusively linked by vertices. The arrangement is reminiscent of a filled β ‐cristobalite structure with the dithiocarbamate ligands extending into the hollow spaces. Thermal decomposition precedes stepwise finally giving Cu 2 S in each case." @default.
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- W1626001215 date "2013-09-06" @default.
- W1626001215 modified "2023-10-16" @default.
- W1626001215 title "On Ammonium-bis(dithiocarbamato)-copper(I)-monohydrate and Mono(dithiocarbamato)-copper(I)" @default.
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- W1626001215 doi "https://doi.org/10.1002/zaac.201300321" @default.
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