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- W1627225279 abstract "Various [60]fullerene derivatives were covalently anchored via a Si‐C bond to hydrogen‐terminated Si(100) following wet‐chemistry recipes. The applied reactions require a two‐step approach consisting of a pre‐modification of the Si(100) surface with an organic monolayer bearing a terminal functionality that undergoes a bond‐forming reaction with a [60]fullerene synthon. The resulting Si‐C bound hybrids were characterized by a combination of XPS, AFM, contact angle, and electrochemical analysis. The hybrid surfaces containing [60rsqb;fullerene‐ferrocene fragments are exceptionally robust towards repeated reduction‐oxidation cycles. Moreover, several surface‐confined redox couples were observed in CH3CN solution. The surface coverage was measured to be ca. 2.5×10−11 mol cm−2." @default.
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- W1627225279 date "2009-01-01" @default.
- W1627225279 modified "2023-10-18" @default.
- W1627225279 title "Fullerenes Covalently Anchored On Si(100): An Experimental Study" @default.
- W1627225279 doi "https://doi.org/10.1063/1.3225421" @default.
- W1627225279 hasPublicationYear "2009" @default.
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