FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1628610636> ?p ?o ?g. }

• W1628610636 endingPage "1728" @default.
• W1628610636 startingPage "1723" @default.
• W1628610636 abstract "C–H–O interactions of a self-assembled triple helix based on the 1-acetamido-3(2-pyrazinyl)-imidazolium cation has been probed by high pressure. The infrared spectroscopic profiles and ab initio calculations allow us to make a vibrational assignment of this compound. The C–H bonds forming C–H–O interactions shorten as the pressure was elevated, while free C–H vibration modes show low sensitivity to high pressure. The pressure-dependent results can be attributed to the strengthening of C–H–O electrostatic–dispersion interactions upon increasing pressure. The appearance of the free-NH infrared absorption indicates that the conventional N–H–O hydrogen bond does not dominate the inter-strand packing in the compound. It is proposed that the charge-enhanced C–H–O interactions, forming a helical hydrogen-bonding network, disturb the formation of inter-strand N–H–O hydrogen-bonding in order to form a maximum number of hydrogen bonds. Applying high-pressure seems not to change the C=O bond length in contrast to the trend of blue-shift in frequency of C–H vibrations. London dispersion energy is suggested to be required for understanding the pressure-dependent results, although more additional terms, such as the effect in the presence of charge, are needed for the correct explanation. This work demonstrates that high-pressure studies may have the potential to provide insight into the C–H–O structural properties of biological related systems." @default.
• W1628610636 created "2016-06-24" @default.
• W1628610636 creator A5006792025 @default.
• W1628610636 creator A5020382268 @default.
• W1628610636 creator A5037150692 @default.
• W1628610636 creator A5055681721 @default.
• W1628610636 creator A5066506467 @default.
• W1628610636 creator A5082304952 @default.
• W1628610636 creator A5087811058 @default.
• W1628610636 date "2002-07-11" @default.
• W1628610636 modified "2023-09-30" @default.
• W1628610636 title "Charge-enhanced C–H–O interactions of a self-assembled triple helical spine probed by high-pressure" @default.
• W1628610636 cites W1964277385 @default.
• W1628610636 cites W1981846449 @default.
• W1628610636 cites W1988981377 @default.
• W1628610636 cites W1989178532 @default.
• W1628610636 cites W1993867751 @default.
• W1628610636 cites W1994222323 @default.
• W1628610636 cites W1996530197 @default.
• W1628610636 cites W1997867909 @default.
• W1628610636 cites W2009487455 @default.
• W1628610636 cites W2012068802 @default.
• W1628610636 cites W2013085543 @default.
• W1628610636 cites W2013753805 @default.
• W1628610636 cites W2014185787 @default.
• W1628610636 cites W2039735251 @default.
• W1628610636 cites W2049281887 @default.
• W1628610636 cites W2055729319 @default.
• W1628610636 cites W2056651981 @default.
• W1628610636 cites W2058538336 @default.
• W1628610636 cites W2062129975 @default.
• W1628610636 cites W2066483802 @default.
• W1628610636 cites W2072628908 @default.
• W1628610636 cites W2074965371 @default.
• W1628610636 cites W2080172672 @default.
• W1628610636 cites W2080972330 @default.
• W1628610636 cites W2082214266 @default.
• W1628610636 cites W2091952981 @default.
• W1628610636 cites W2115474652 @default.
• W1628610636 cites W2154918056 @default.
• W1628610636 cites W2163697621 @default.
• W1628610636 cites W2297422337 @default.
• W1628610636 doi "https://doi.org/10.1063/1.1489420" @default.
• W1628610636 hasPublicationYear "2002" @default.
• W1628610636 type Work @default.
• W1628610636 sameAs 1628610636 @default.
• W1628610636 citedByCount "26" @default.
• W1628610636 countsByYear W16286106362013 @default.
• W1628610636 countsByYear W16286106362014 @default.
• W1628610636 countsByYear W16286106362015 @default.
• W1628610636 countsByYear W16286106362016 @default.
• W1628610636 countsByYear W16286106362017 @default.
• W1628610636 crossrefType "journal-article" @default.
• W1628610636 hasAuthorship W1628610636A5006792025 @default.
• W1628610636 hasAuthorship W1628610636A5020382268 @default.
• W1628610636 hasAuthorship W1628610636A5037150692 @default.
• W1628610636 hasAuthorship W1628610636A5055681721 @default.
• W1628610636 hasAuthorship W1628610636A5066506467 @default.
• W1628610636 hasAuthorship W1628610636A5082304952 @default.
• W1628610636 hasAuthorship W1628610636A5087811058 @default.
• W1628610636 hasConcept C112887158 @default.
• W1628610636 hasConcept C120665830 @default.
• W1628610636 hasConcept C121332964 @default.
• W1628610636 hasConcept C147597530 @default.
• W1628610636 hasConcept C158355884 @default.
• W1628610636 hasConcept C177562468 @default.
• W1628610636 hasConcept C178790620 @default.
• W1628610636 hasConcept C183971685 @default.
• W1628610636 hasConcept C185592680 @default.
• W1628610636 hasConcept C188082385 @default.
• W1628610636 hasConcept C2781442258 @default.
• W1628610636 hasConcept C32909587 @default.
• W1628610636 hasConcept C512968161 @default.
• W1628610636 hasConcept C62520636 @default.
• W1628610636 hasConcept C8010536 @default.
• W1628610636 hasConceptScore W1628610636C112887158 @default.
• W1628610636 hasConceptScore W1628610636C120665830 @default.
• W1628610636 hasConceptScore W1628610636C121332964 @default.
• W1628610636 hasConceptScore W1628610636C147597530 @default.
• W1628610636 hasConceptScore W1628610636C158355884 @default.
• W1628610636 hasConceptScore W1628610636C177562468 @default.
• W1628610636 hasConceptScore W1628610636C178790620 @default.
• W1628610636 hasConceptScore W1628610636C183971685 @default.
• W1628610636 hasConceptScore W1628610636C185592680 @default.
• W1628610636 hasConceptScore W1628610636C188082385 @default.
• W1628610636 hasConceptScore W1628610636C2781442258 @default.
• W1628610636 hasConceptScore W1628610636C32909587 @default.
• W1628610636 hasConceptScore W1628610636C512968161 @default.
• W1628610636 hasConceptScore W1628610636C62520636 @default.
• W1628610636 hasConceptScore W1628610636C8010536 @default.
• W1628610636 hasIssue "4" @default.
• W1628610636 hasLocation W16286106361 @default.
• W1628610636 hasOpenAccess W1628610636 @default.
• W1628610636 hasPrimaryLocation W16286106361 @default.
• W1628610636 hasRelatedWork W2001967484 @default.
• W1628610636 hasRelatedWork W2007188170 @default.
• W1628610636 hasRelatedWork W2010191713 @default.
• W1628610636 hasRelatedWork W2033069720 @default.

• next