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- W1628658664 abstract "Abstract : This report provides the crystal-field splitting of Cr4+ in the host materials Na2TiSiO5 Y2SiBe2O7, Bi4X3O12, and Bi12XO20. The strength of the crystal field is estimated by evaluating the coefficients of a multipole expansion of the crystal field for the Ti, Si, or Ge site and using empirical values of the radial integrals, . With the exception of the Ti site in Na2TiSiO7, the Si or Ge sites(D2d or S4 symmetry) are, to a certain degree, approximately tetrahedral. In the material Bi12Xo20 the X site (Ge or Si) has the cubic symmetry T. Estimated values of the parameters for the quadruply ionized 3dn electronic configurations are given for X=Ge. The energy levels are calculated with and without the spin-orbit interaction." @default.
- W1628658664 created "2016-06-24" @default.
- W1628658664 creator A5009321137 @default.
- W1628658664 date "1991-05-01" @default.
- W1628658664 modified "2023-09-24" @default.
- W1628658664 title "Possible Hosts for Quadruply Ionized 3d(N) Transition Metal Ions: Na2TiSiO5, Y2SiBe2O7, Bi4X3O12, and Bi12XO20 (X = Si, Ge)" @default.
- W1628658664 doi "https://doi.org/10.21236/ada236543" @default.
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