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- W1630021803 abstract "Two kinds of new thiacalix[6]arene (TC6A) derivatives, TC6A-CH2COOH (1) and TC6A-CSN(CH3)2 (2), were synthesized through modify at the lower rims of TC6A. The extraction of 1 or 2 for rare metal ions from platinum-group metals (PGM) solution containing eight rare metals (Rh, Pd, Pt, Zr, Ce, Ba, La, Y) and one base metal (Al) were investigated. Compound 1 showed selective extractability for Pd and Zr ions, which the extraction rates were 70% and 91%, respectively. The extraction rates of the other metal ions were below 5% by using 1 and 2. Compound 1 also showed stripping extraction ability of Pd ion by 7N HCl where the stripping ratio was ca. 70%. On the other hand, compound 2 indicated high selectivity of almost 100% Pd ion extraction from PGM solution." @default.
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- W1630021803 date "2014-01-01" @default.
- W1630021803 modified "2023-09-25" @default.
- W1630021803 title "High Selective Extraction Ability for Platinum-group Metals Based on Thiacalix[6]arene Derivatives" @default.
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- W1630021803 doi "https://doi.org/10.5188/ijsmer.20.103" @default.
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