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• W1631005943 abstract "Synthesis and characterization of Nd2Fe14−xSixBHy compounds are presented for x=1–2 and y=0–4. The samples have been studied with emphasis given to the structural aspects and the magnetic properties. Our present investigation has been performed both at 2 and 300 K by means of high-resolution powder neutron diffraction. We report the evolution of the maximum hydrogen uptake, which decreases when the Si concentration increases. This behavior is discussed in the light of earlier neutron diffraction results concerning the preferential occupancy of some Fe sites by Si atoms and the H location in the prototype, Nd2Fe14B phase. The decrease of hydrogen uptake occurs mainly on two interstitial sites out of the four different interstitial sites involved in the insertion scheme. The saturation magnetization results are compared with the magnetic moments obtained by neutron diffraction analysis. Finally, the effects of Si substitution and/or H insertion on the spin reorientation that occurs at low temperatures have been investigated by means of ac susceptibility measurements." @default.
• W1631005943 created "2016-06-24" @default.
• W1631005943 creator A5021455992 @default.
• W1631005943 creator A5083737118 @default.
• W1631005943 date "2000-09-01" @default.
• W1631005943 modified "2023-09-23" @default.
• W1631005943 title "Structure of Nd2Fe14−xSixBHy measured by neutron diffraction" @default.
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• W1631005943 doi "https://doi.org/10.1063/1.1286134" @default.
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