Matches in SemOpenAlex for { <https://semopenalex.org/work/W163137956> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W163137956 abstract "The work described herein describes the synthesis and subsequent functionalization of thiol-acrylate emulsion templated porous polymers (polyHIPEs). Thiol-ene “click” chemistry has been employed in order to produce polyHIPEs from multifunctional thiol and acrylate monomers, and the level of residual thiol within the material determined. These residual thiols have then been used as “reactive handles” which allow for the functionalization of the thiol-acrylate polyHIPE post-polymerization. Both radical mediated thiol-ene “click” and amine catalysed Michael additions have been used in order to graft acrylates to the polymer surface, and the formation of disulphide bonds between the polymer surface and thiols has been explored.The non-crosslinking monomer pentafluorophenyl acrylate (PFPA) has also been incorporated into thiol-acrylate polyHIPEs in order to provide a route to post-polymerization functionalization. The reaction between the PFPA within the polymer network and amines occurs under mild conditions and so this has been explored as a route to the incorporation of biomolecules in the polymer network." @default.
- W163137956 created "2016-06-24" @default.
- W163137956 creator A5058626312 @default.
- W163137956 date "2014-01-01" @default.
- W163137956 modified "2023-09-27" @default.
- W163137956 title "Chemical Functionalization of thiol-acrylate polyHIPEs" @default.
- W163137956 hasPublicationYear "2014" @default.
- W163137956 type Work @default.
- W163137956 sameAs 163137956 @default.
- W163137956 citedByCount "0" @default.
- W163137956 crossrefType "dissertation" @default.
- W163137956 hasAuthorship W163137956A5058626312 @default.
- W163137956 hasConcept C115537861 @default.
- W163137956 hasConcept C147789679 @default.
- W163137956 hasConcept C166940927 @default.
- W163137956 hasConcept C178790620 @default.
- W163137956 hasConcept C185592680 @default.
- W163137956 hasConcept C188027245 @default.
- W163137956 hasConcept C192562407 @default.
- W163137956 hasConcept C2779989194 @default.
- W163137956 hasConcept C2781324293 @default.
- W163137956 hasConcept C44228677 @default.
- W163137956 hasConcept C521977710 @default.
- W163137956 hasConcept C69610077 @default.
- W163137956 hasConceptScore W163137956C115537861 @default.
- W163137956 hasConceptScore W163137956C147789679 @default.
- W163137956 hasConceptScore W163137956C166940927 @default.
- W163137956 hasConceptScore W163137956C178790620 @default.
- W163137956 hasConceptScore W163137956C185592680 @default.
- W163137956 hasConceptScore W163137956C188027245 @default.
- W163137956 hasConceptScore W163137956C192562407 @default.
- W163137956 hasConceptScore W163137956C2779989194 @default.
- W163137956 hasConceptScore W163137956C2781324293 @default.
- W163137956 hasConceptScore W163137956C44228677 @default.
- W163137956 hasConceptScore W163137956C521977710 @default.
- W163137956 hasConceptScore W163137956C69610077 @default.
- W163137956 hasLocation W1631379561 @default.
- W163137956 hasOpenAccess W163137956 @default.
- W163137956 hasPrimaryLocation W1631379561 @default.
- W163137956 hasRelatedWork W1860226163 @default.
- W163137956 hasRelatedWork W1992107064 @default.
- W163137956 hasRelatedWork W2005893764 @default.
- W163137956 hasRelatedWork W2025214851 @default.
- W163137956 hasRelatedWork W2028054410 @default.
- W163137956 hasRelatedWork W2042998010 @default.
- W163137956 hasRelatedWork W2053302912 @default.
- W163137956 hasRelatedWork W2072287050 @default.
- W163137956 hasRelatedWork W2072539981 @default.
- W163137956 hasRelatedWork W2122071265 @default.
- W163137956 hasRelatedWork W2321618605 @default.
- W163137956 hasRelatedWork W2322274451 @default.
- W163137956 hasRelatedWork W2350198169 @default.
- W163137956 hasRelatedWork W2372374975 @default.
- W163137956 hasRelatedWork W2789797414 @default.
- W163137956 hasRelatedWork W2913179385 @default.
- W163137956 hasRelatedWork W3048234121 @default.
- W163137956 hasRelatedWork W3202301501 @default.
- W163137956 hasRelatedWork W3211816388 @default.
- W163137956 hasRelatedWork W2518353735 @default.
- W163137956 isParatext "false" @default.
- W163137956 isRetracted "false" @default.
- W163137956 magId "163137956" @default.
- W163137956 workType "dissertation" @default.