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- W1633372666 abstract "The structure of melt-spun Zr100-xFex glasses (20<or=x<or=43) has been investigated by Mossbauer spectroscopy. All alloys showed a pure paramagnetic absorption spectrum with two broadened asymmetric lines which exhibit approximately a pseudo-lorentzian line shape. The spectra were fitted by three independent quadrupole doublets or by distributions of hyperfine parameters using the method of Hesse and Rubartsch (1974). Two different Fe sites can be distinguished corresponding possibly to the compositions Zr70Fe30 and Zr50Fe50. By comparison with the crystalline structures and DRPHS models, the first site is attributed to trigonal and distorted trigonal prismatic surroundings connected to the crystalline structural units of Zr3Fe or cubic Zr2Fe, whereas a smaller fraction of 9% is associated with a more open structure. Above 33 at.% Fe the structure is changed, i.e. a new site dominates, which is connected to a possible intermetallic compound ZrFe, for which Fe-Fe contacts might occur." @default.
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- W1633372666 date "1986-01-01" @default.
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- W1633372666 title "Mossbauer study of amorphous Zr<sub>100-x</sub>Fe<sub>x</sub>alloys" @default.
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- W1633372666 doi "https://doi.org/10.1088/0305-4608/16/1/018" @default.
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