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• W1633821332 abstract "Sub-Doppler excitation spectra of the S11B2u(v6=1)←S01A1g(v=0) transition of the C6D6 and C6H6 molecules were measured by crossing a laser beam perpendicular to a collimated molecular beam. Part of a scanning laser beam was passed through the actively stabilized etalon, whose cavity length was locked against the wavelength of the cw Nd:YAG laser which was locked to a hyperfine line of an iodine molecule, and the fringe marks at every 60 MHz were used to measure the change of the laser frequency precisely. Rotationally resolved 1253 and 1158 lines of C6D6 and C6H6, respectively, were used to determine molecular constants of the S11B2u(v6=1) and S01A1g(v=0) states. No appreciable perturbations were observed in the S01A1g(v=0) and S11B2u(v6=1) states of both molecules. From the improved molecular constants, the internuclear distances rC–C and rC–H were determined to be 1.39711 and 1.08066 Å, respectively, in the S01A1g(v=0) state, and 1.4317 and 1.072 Å, respectively, in the S11B2u(v6=1) state." @default.
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• W1633821332 date "2004-10-01" @default.
• W1633821332 modified "2023-10-02" @default.
• W1633821332 title "Sub-Doppler rotationally resolved spectroscopy of the bands of benzene and benzene-d6" @default.
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• W1633821332 doi "https://doi.org/10.1016/j.jms.2004.06.003" @default.
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