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- W1635820812 abstract "Temperature variation of the crystal structure has been investigated for Tb 2 Ba 2 Co 4 O 11 , which shows a metal-insulator (MI) transition at T MI = 340 K. The compound has a layered-type double-perovskite structure along the c -axis, with alternating the CoO 6 octahedron and the CoO 5 pyramids along the a -axis. With decrease of temperature below T MI , the distortion of the octahedral and pyramidal sites is fairly released, suggesting that spin state transition of the Co 3+ ions is the origin for the MI transition." @default.
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- W1635820812 date "2001-12-15" @default.
- W1635820812 modified "2023-09-24" @default.
- W1635820812 title "Structural Change at Metal-Insulator Transition of Tb<sub>2</sub>Ba<sub>2</sub>Co<sub>4</sub>O<sub>11</sub>" @default.
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- W1635820812 doi "https://doi.org/10.1143/jpsj.70.3577" @default.
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