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- W1635861857 abstract "We analyze the experimental core-level photoemission and x-ray absorption (XA) spectra of ${mathrm{NaCuO}}_{2}$ in terms of an Anderson-impurity Hamiltonian including the band-structure effects of the oxygen sublattice and show that the XA results unambiguously indicate a negative value of the charge-transfer energy ensuremath{Delta}. We also perform mean-field calculations for the electronic structure for the edge-shared one-dimensional ${mathrm{CuO}}_{2}$ lattice of ${mathrm{NaCuO}}_{2}$ within the multiband Hubbard Hamiltonian and show that the origin of the insulating nature lies in band-structure rather than correlation effects, and that the gap has a pd-p character." @default.
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- W1635861857 date "1993-04-15" @default.
- W1635861857 modified "2023-09-25" @default.
- W1635861857 title "Electronic structure of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>NaCuO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W1635861857 doi "https://doi.org/10.1103/physrevb.47.10927" @default.
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