FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1636097837> ?p ?o ?g. }

• W1636097837 endingPage "2029" @default.
• W1636097837 startingPage "2017" @default.
• W1636097837 abstract "The reaction dynamics of ground-state atomic oxygen [O(3P)] with allyl radicals (C3H5) has been investigated by applying a combination of crossed beams and laser induced fluorescence techniques. The reactants O(3P) and C3H5 were produced by the photodissociation of NO2 and the supersonic flash pyrolysis of precursor allyl iodide, respectively. A new exothermic channel of O(3P)+C3H5→C3H4+OH was observed and the nascent internal state distributions of the product OH (X 2Π:υ″=0,1) showed substantial bimodal internal excitations of the low- and high-N″ components without Λ-doublet and spin–orbit propensities in the ground and first excited vibrational states. With the aid of the CBS-QB3 level of ab initio theory and Rice–Ramsperger–Kassel–Marcus calculations, it is predicted that on the lowest doublet potential energy surface the major reaction channel of O(3P) with C3H5 is the formation of acrolein (CH2CHCHO)+H, which is consistent with the previous bulk kinetic experiments performed by Gutman et al. [J. Phys. Chem. 94, 3652 (1990)]. The counterpart C3H4 of the probed OH product in the title reaction is calculated to be allene after taking into account the factors of reaction enthalpy, barrier height and the number of intermediates involved along the reaction pathway. On the basis of population analyses and comparison with prior calculations, the statistical picture is not suitable to describe the reactive atom-radical scattering processes, and the dynamics of the title reaction is believed to proceed through two competing dynamical pathways. The major low N″-components with significant vibrational excitation may be described by the direct abstraction process, while the minor but extraordinarily hot rotational distribution of high N″-components implies that some fraction of reactants is sampled to proceed through the indirect short-lived addition-complex forming process." @default.
• W1636097837 created "2016-06-24" @default.
• W1636097837 creator A5008969887 @default.
• W1636097837 creator A5024438719 @default.
• W1636097837 creator A5055812547 @default.
• W1636097837 creator A5069818368 @default.
• W1636097837 creator A5084770316 @default.
• W1636097837 creator A5090325538 @default.
• W1636097837 date "2002-07-16" @default.
• W1636097837 modified "2023-09-23" @default.
• W1636097837 title "Atom-radical reaction dynamics of O(3P)+C3H5→C3H4+OH: Nascent rovibrational state distributions of product OH" @default.
• W1636097837 cites W1584477474 @default.
• W1636097837 cites W1585752856 @default.
• W1636097837 cites W1642237435 @default.
• W1636097837 cites W1671476171 @default.
• W1636097837 cites W1970026093 @default.
• W1636097837 cites W1970549136 @default.
• W1636097837 cites W1970992499 @default.
• W1636097837 cites W1974094706 @default.
• W1636097837 cites W1974575300 @default.
• W1636097837 cites W1977012521 @default.
• W1636097837 cites W1977479024 @default.
• W1636097837 cites W1979489183 @default.
• W1636097837 cites W1981607030 @default.
• W1636097837 cites W1982356449 @default.
• W1636097837 cites W1982474556 @default.
• W1636097837 cites W1991423509 @default.
• W1636097837 cites W1998667112 @default.
• W1636097837 cites W1998725642 @default.
• W1636097837 cites W1999322632 @default.
• W1636097837 cites W1999906506 @default.
• W1636097837 cites W2000058049 @default.
• W1636097837 cites W2000845725 @default.
• W1636097837 cites W2006005108 @default.
• W1636097837 cites W2008631320 @default.
• W1636097837 cites W2014061832 @default.
• W1636097837 cites W2014181822 @default.
• W1636097837 cites W2018153737 @default.
• W1636097837 cites W2023271753 @default.
• W1636097837 cites W2024500992 @default.
• W1636097837 cites W2028548872 @default.
• W1636097837 cites W2029598912 @default.
• W1636097837 cites W2031161548 @default.
• W1636097837 cites W2034778956 @default.
• W1636097837 cites W2035818773 @default.
• W1636097837 cites W2038388917 @default.
• W1636097837 cites W2045006138 @default.
• W1636097837 cites W2049945329 @default.
• W1636097837 cites W2052573265 @default.
• W1636097837 cites W2054713188 @default.
• W1636097837 cites W2059211850 @default.
• W1636097837 cites W2063846186 @default.
• W1636097837 cites W2066041001 @default.
• W1636097837 cites W2068816490 @default.
• W1636097837 cites W2070578704 @default.
• W1636097837 cites W2071706375 @default.
• W1636097837 cites W2077528747 @default.
• W1636097837 cites W2077788408 @default.
• W1636097837 cites W2080387151 @default.
• W1636097837 cites W2080755940 @default.
• W1636097837 cites W2080979423 @default.
• W1636097837 cites W2086505034 @default.
• W1636097837 cites W2090706212 @default.
• W1636097837 cites W2092547283 @default.
• W1636097837 cites W2110817411 @default.
• W1636097837 cites W2143981217 @default.
• W1636097837 cites W2224664717 @default.
• W1636097837 cites W2325427504 @default.
• W1636097837 cites W2636681384 @default.
• W1636097837 cites W283872590 @default.
• W1636097837 cites W4285039720 @default.
• W1636097837 doi "https://doi.org/10.1063/1.1486441" @default.
• W1636097837 hasPublicationYear "2002" @default.
• W1636097837 type Work @default.
• W1636097837 sameAs 1636097837 @default.
• W1636097837 citedByCount "35" @default.
• W1636097837 countsByYear W16360978372012 @default.
• W1636097837 countsByYear W16360978372014 @default.
• W1636097837 countsByYear W16360978372015 @default.
• W1636097837 countsByYear W16360978372017 @default.
• W1636097837 countsByYear W16360978372019 @default.
• W1636097837 countsByYear W16360978372021 @default.
• W1636097837 countsByYear W16360978372022 @default.
• W1636097837 crossrefType "journal-article" @default.
• W1636097837 hasAuthorship W1636097837A5008969887 @default.
• W1636097837 hasAuthorship W1636097837A5024438719 @default.
• W1636097837 hasAuthorship W1636097837A5055812547 @default.
• W1636097837 hasAuthorship W1636097837A5069818368 @default.
• W1636097837 hasAuthorship W1636097837A5084770316 @default.
• W1636097837 hasAuthorship W1636097837A5090325538 @default.
• W1636097837 hasConcept C121332964 @default.
• W1636097837 hasConcept C125277925 @default.
• W1636097837 hasConcept C139066938 @default.
• W1636097837 hasConcept C147597530 @default.
• W1636097837 hasConcept C147789679 @default.
• W1636097837 hasConcept C178790620 @default.
• W1636097837 hasConcept C181500209 @default.
• W1636097837 hasConcept C184779094 @default.

• next