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• W1636893448 abstract "Electron paramagnetic resonance (EPR) and magnetic susceptibility studies on x V 2 O 5 · (100 - x) [2 B 2 O 3 · SrO ] glasses with 0 ≤ x ≤ 30 mol% were performed. The covalence degree of vanadium bonds was estimated according to the LCAO-MO model. The EPR data show the presence of V 4+ ions in a square-pyramidal coordination ( C 4v ). The experimental EPR spectra are simulated assuming a superposition of two signals, one with hyperfine structure (HFS) typical for isolated ions and the other one consisting of a broad line without the HFS characteristic for clustered ions. These results are consistent with the magnetic data which indicate that for x ≤ 5 mol% V 2 O 5 the temperature dependence of the reciprocal magnetic susceptibility is described by a Curie–Weiss type law with negative paramagnetic Curie temperature. The magnetic data also allow the estimation of N V 4+ / N V total ratio." @default.
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• W1636893448 date "2002-05-10" @default.
• W1636893448 modified "2023-09-27" @default.
• W1636893448 title "EPR AND MAGNETIC SUSCEPTIBILITY STUDIES OF V4+ IONS IN THE 2B2O3 · SrO GLASS MATRIX" @default.
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• W1636893448 doi "https://doi.org/10.1142/s0217984902003865" @default.
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