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- W1638862252 abstract "Pd(BHEP)Cl2 was synthesized and characterized (BHEP = 1,4-bis(2-hydroxyethyl)piperazine). The complex decomposes in two steps, leaving a residue of palladium metal. Amino acid ester (L) reacts with [Pd(BHEP)(H2O)2]2+ (BHEP = 1,4-bis(2-hydroxyethyl)piperazine), giving mixed-ligand complexes, [Pd(BHEP)L]2+. The kinetics of hydrolysis of [Pd(BHEP)L]2+ have been studied by pH-stat technique, and rate constants were obtained. Rate acceleration observed for glycine methyl ester is high. The effect with methionine methyl ester is much less marked, as the mixed-ligand complexes with these ligands do not involve alkoxycarbonyl donors. Possible mechanisms for these reactions are considered." @default.
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- W1638862252 date "2015-07-06" @default.
- W1638862252 modified "2023-10-04" @default.
- W1638862252 title "Thermal stability of Pd(1,4-bis(2-hydroxyethyl)piperazine)Cl<sub>2</sub> and its role in the catalysis of base hydrolysis of α-amino acid esters" @default.
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- W1638862252 doi "https://doi.org/10.1080/00958972.2015.1061659" @default.
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