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• W1638931343 startingPage "m491" @default.
• W1638931343 abstract "In the title compound, [Li(2)(C(6)H(3)N(2)O(4))(2)(H(2)O)(3)](n), the coordination number for both independent Li(+) cations is five. One of the Li(+) ions has a distorted trigonal-bipyramidal geometry, coordinated by one of the carboxyl O atoms of a 3-carboxy-pyrazine-2-carboxyl-ate ligand, two O atoms from two water mol-ecules, and an N and a carboxyl-ate O atom of a second 3-carboxy-pyrazine-2-carboxyl-ate ligand. The other Li(+) ion also has a distorted trigonal-bipyramidal geometry, coordinated by one water mol-ecule and two 3-carboxy-pyrazine-2-carboxyl-ate ligands through an N and a carboxyl-ate O atom from each. One of the carboxyl groups of the two ligands takes part in an intra-molecular O-H⋯O hydrogen bond. The stabilization of the crystal structure is further assisted by O-H⋯O, O-H⋯N and C-H⋯O hydrogen-bonding inter-actions involving the water mol-ecules and carboxyl-ate O atoms." @default.
• W1638931343 created "2016-06-24" @default.
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• W1638931343 date "2008-02-20" @default.
• W1638931343 modified "2023-10-16" @default.
• W1638931343 title "Poly[triaquabis(μ₂-3-carboxypyrazine-2-carboxylato)dilithium(I)]" @default.
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• W1638931343 doi "https://doi.org/10.1107/s1600536808004467" @default.
• W1638931343 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2960851" @default.
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