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- W1639264477 abstract "The characteristics of the diffuse phase transition of Pb(Fe2/3W1/3)O3 relaxor ceramics doped with different amounts of Mn are investigated. The freezing temperature Tf, obtained by fitting the ω,Tmax to the Vogel–Fulcher relationship, clearly changes with the Mn content. It increases as the Mn content increases, approaching the Tmax(1 MHz) value of the relaxor curve. A concomitant decrease in the frequency dispersion of Tmax is also observed. The freezing temperature also increases as the 1:1 order of Fe3+ and W6+on B sites increases by air annealing but decreases by oxygen annealing. It is suggested that the Mn ions, which are predominantly compensated by oxygen vacancies, form with them defect pairs and that these pairs can couple to the spontaneous polarization vectors, increasing the correlation between the dipole moments and originating the increase of the freezing temperature. It is further suggested that filling up the oxygen vacancies by oxygen annealing will decrease the defect pairs and cause the opposite effect." @default.
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- W1639264477 title "The characteristics of the diffuse phase transition in Mn doped Pb(Fe2/3W1/3)O3 relaxor ceramics" @default.
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- W1639264477 doi "https://doi.org/10.1063/1.369543" @default.
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