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• W1639614872 abstract "We present a systematic and thorough structural study of the double perovskite series Sr2Fe0.75T0.25MoO6 (T=Sc, Ti, V, Cr, Mn, Fe, Co) by means of high resolution neutron diffraction as a function of temperature. The results have been complemented with room-temperature X-ray diffraction, magnetotransport and magnetisation measurements. Our study reveals the exceptionally strong influence of the 3d dopant on both long-range magnetic order (TC) and structural transition to a low-temperature tetragonal phase (TS). A decoupling of both magnetic and structural behaviour has been found in all cases except for T=Cr and Fe, ruling out a simple magnetostructural effect. A third transition (Ttetra) where the system becomes metrically cubic has been found and its nonequivalence to TS investigated in detail. In the case of T=Sc, Mn, a further symmetry reduction to a low-temperature monoclinic structure has been detected. The obtained results are discussed in terms of the size and valence state of the dopant, and correlated with the magnetic and electrical transport properties." @default.
• W1639614872 created "2016-06-24" @default.
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• W1639614872 date "2004-05-01" @default.
• W1639614872 modified "2023-10-11" @default.
• W1639614872 title "Structural and magnetic details of 3d-element doped Sr2Fe0.75T0.25MoO6" @default.
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• W1639614872 doi "https://doi.org/10.1016/j.solidstatesciences.2004.02.007" @default.
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