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- W1640013208 abstract "This chapter discusses the biosynthesis of the monosaccharides. The biological origin of the forty or more monosaccharides occurring in natural products is not only of academic interest but also of value from its applicability to extracellular, enzymic synthesis. The monosaccharides are closely related, one to another, in their main structural features, thus suggesting biogenetic relationships. An examination of this kind has been called “comparative anatomy.” Slight structural changes in a molecule serve to indicate a conversion of one monosaccharide into another, as, for example, the reversible transformation or epimerization of an aldose into a ketose, the hypothetical decarboxylation of a hexuronic acid to give a pentose, or the reduction of a sugar to a polyhydric alcohol. The most important enzymes involved in monosaccharide biosynthesis are those that will synthesize a carbon-to-carbon covalent bond and, in reverse, cause fission of this bond. It is becoming increasingly clear that many of these reactions are brought about by transfer of a group from a preformed monosaccharide to an acceptor molecule, rather than by direct combination of two substrates. These enzymes are of two types, one causing an aldol reaction and the other an acyloin (or ketol) reaction." @default.
- W1640013208 created "2016-06-24" @default.
- W1640013208 creator A5020350796 @default.
- W1640013208 creator A5026642235 @default.
- W1640013208 date "1956-01-01" @default.
- W1640013208 modified "2023-09-25" @default.
- W1640013208 title "The Biosynthesis of the Monosaccharides" @default.
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