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- W1640576746 abstract "Resonance Raman scattering from carbyne films obtained by dehydrocholorination of poly (vinylidene chloride) was studied under various laser excitation energies at room temperature. Four dominant Raman lines at around 1150, 1290, 1530 and 2150 cm−1 were observed. Each line showed clear dispersion effect between 10 and 40 cm−1/eV. The scattering line at 1150 cm−1 showed a slightly shift of 5 cm−1 towards the higher wave number when the specimen was exposed to ambient atmosphere. The intensity ratio of line at 2150 cm−1, which was referred to as the polyyne structure, to the one at 1530 cm−1 referred as the polyene structure increased with increasing of the energy of exciting laser. The averaged number of the conjugated atoms consisting of the polyyne structure was estimated to be about 10 from the comparison of the calculation of Σg mode frequency." @default.
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- W1640576746 date "2000-01-01" @default.
- W1640576746 modified "2023-09-27" @default.
- W1640576746 title "Resonance Raman scattering from carbyne materials" @default.
- W1640576746 doi "https://doi.org/10.1063/1.1342557" @default.
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