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• W1642199114 abstract "The Fe-Ti-V system is important for steels, both Ti and V forming very stable carbides, and thus suppressing the stability of cementite. Both Ti-carbides and V-carbides are useful in controlling grain size. Both Ti and V can also form nitrides and carbonitrides, which can pin grain boundaries, and hence produce steels with a finer grain size. The control of grain size is vital in production, especially rolling, and knowledge of the effects of additions to steels is vital for improved quality and productivity. Vanadium is beneficial in promoting fine, mainly nitride, precipitates which give dispersion strengthening. The Laves phase is also formed, and depending on morphology, these can be detrimental to mechanical properties. Some vanadium alloys, such as V-5Fe-3Ti, show potential as structural materials for fision power plants because of their resistance to swelling after neutron irradiation. Both the TiFe2 Laves phase and (βTi,V) have been identified as having potential hydrogenation capability, and work is ongoing to characterize and enhance this. It has been postulated that alloys based on the Laves phase could have potential as neutron radiation shielding applications. Although there are experimental data for the system, they are fairly limited, and mostly confined to the Fe rich compositions, and the purity of Fe in the earlier work was 99 mass%. The Fe rich corner was studied by [1954Luc] using samples prepared from Armco iron ( 99% purity), sponge titanium and high (although unspecified) purity vanadium. [1993Rag] cites thermodynamic calculation of (γFe)/((γFe)+(αFe)) and ((γFe)+(αFe))/ (αFe) phase boundaries at 950 C, 1050 C, 1150 C and 1250 C undertaken by [1988Kum]; they were found to be linear. The system has been reviewed by [1987Rag1, 1987Rag2, 1993Rag]. The experimental work is summarized in Table 1. There are a number of references that seem to be by the same authors although the name of the primary author has been spelled in different ways. These are [1959Cin, 1960Tsi, 1961Cin, 1961Chi]." @default.
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• W1642199114 date "2008-01-01" @default.
• W1642199114 modified "2023-09-26" @default.
• W1642199114 title "Iron – Manganese – Vanadium" @default.
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• W1642199114 doi "https://doi.org/10.1007/978-3-540-78644-3_23" @default.
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