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- W164237210 abstract "The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C usedmore » here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.« less" @default.
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- W164237210 date "1981-07-23" @default.
- W164237210 modified "2023-10-16" @default.
- W164237210 title "Pyrolysis of Shale Oil Residual Fractions" @default.
- W164237210 doi "https://doi.org/10.1021/bk-1981-0163.ch019" @default.
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