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- W164413356 abstract "The electron transfer initiated cyclization (ETIC)/enol ether cleavage reaction has been developed in the Floreancig group as a mild and selective method for the formation of substituted tetrahydropyran rings systems, which are common in natural products. Reactions untilizing the initial substrate result in a methyl ketone substituted tetrahydropyran ring, however the addition of a side chain along the alkyl backbone of the substrate can lead to di-substituted tetrahydropyran rings. Products with side chains in the alpha and gamma positions containing aliphatic, alkoxy and siloxy groups have been synthesized. The cis/trans stereochemistry of the two side chains has been predicted based on transition state models and has been verified by NMR experimentation." @default.
- W164413356 created "2016-06-24" @default.
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- W164413356 date "2007-01-23" @default.
- W164413356 modified "2023-09-27" @default.
- W164413356 title "Stereochemical and Reactivity Studies of ETIC/Enol Ether Cleavage Reactions" @default.
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