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• W1645314230 abstract "The article contains sections titled: 1.Introduction2.CE Modes and Techniques2.1.Overview2.2.Capillary Zone Electrophoresis, Isotachophoresis, and Isoelectric Focusing2.3.Separations with Additional Constraints2.4.Electrokinetic Capillary Chromatography2.5.Capillary Electrochromatography3.Theoretical Aspects of CE3.1.Electrokinetic Phenomena and Fundamental Separation Aspects3.2.Dynamic Computer Simulation of Electrophoretic Processes3.3.Peakmaster for Capillary Zone Electrophoresis3.4.Moving Boundary Equation, Regulation Functions and Other Models3.5.Internet Resources and Availability of Physico-Chemical Constants4.CE Instrumentation4.1.General Aspects and Early Developments4.2.Instrumentation Featuring Fused-Silica Capillaries4.3.Chip Instrumentation4.4.CE-MS and CE Instrumentation for Special Tasks5.Aspects of a CE-Based Assay5.1.Separation Column5.2.Separation Medium5.3.Analyte Injection, Stacking, and Detection5.4.Sample Preparation, Analyte Quantitation and Complete Assay Specifications6.CE Applications6.1.CE for Determination of Physico-Chemical Properties of Molecules, Ions, and Liquids6.2.CE of Ions and Small Molecules6.3.CE of Pharmaceuticals and their Metabolites6.4.CE of Carbohydrates6.5.CE of Peptides and Proteins6.6.CE of Oligonucleotides, DNA, and RNA6.7.CE of Particles and Synthetic Polymers6.8.Special Techniques for Ultrafast Analysis, Extreme Resolution, and Small Sample Size7.Brief Discussion and OutlookElectrophoretic separations and analyses in capillaries and microchannels have received considerable attention since the 1970s. Since this time a number of techniques for electrophoretic separations and analyses of small (microliters to femtoliters) sample volumes have emerged, including capillary zone electrophoresis, capillary isotachophoresis, capillary isoelectric focusing, capillary gel electrophoresis, affinity capillary electrophoresis, electrokinetic capillary chromatography, and capillary electrochromatography. High separation efficiencies have been demonstrated in conjunction with high-resolution on-column and/or end-column sample detection. Capillary and microchip electrophoresis represent instrumental approaches of electrophoresis which complement other techniques, in particular high-performance liquid chromatography and slab gel electrophoresis. This keyword presents theoretical, instrumentation, and practical assay aspects of capillary and microchip electrophoresis together with illustrative examples. Examples of capillary electrophoresis in major fields of application are given and an overview of the key achievements encountered is provided." @default.
• W1645314230 created "2016-06-24" @default.
• W1645314230 creator A5013013472 @default.
• W1645314230 date "2012-07-15" @default.
• W1645314230 modified "2023-09-24" @default.
• W1645314230 title "Capillary and Microchip Electrophoresis" @default.
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