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• W1645901412 endingPage "469" @default.
• W1645901412 startingPage "375" @default.
• W1645901412 abstract "This chapter describes the descending syntheses of sugars and other organic compounds. Many of the reactions of saccharide derivatives lead to various degradation products by pathways involving splitting or fragmentation of the carbon skeleton. The descended substances produced in these reactions often serve as invaluable materials for the production of other sugars and chiral building units for the synthesis of different types of organic compounds. Hydrogen peroxide is known to effect different types of degradation of carbohydrates, giving rise to various products as a result of the random oxidation. Combination of this oxidizing agent with Fe2+ and Fe3+ ions for the degradation of hydroxycarboxylic acids has long been applied, but no practical utilization has been found in the field of sugar chemistry. The descending procedure permits the synthesis, although in moderate yield. When the alkaline-earth metal salts of aldonic acids are reacted with hydrogen peroxide in the presence of Fe3+ salts, an aldose shortened by one carbon atom is obtained, generally with a moderate yield." @default.
• W1645901412 created "2016-06-24" @default.
• W1645901412 creator A5018448078 @default.
• W1645901412 creator A5031504546 @default.
• W1645901412 date "1998-01-01" @default.
• W1645901412 modified "2023-10-18" @default.
• W1645901412 title "Descending syntheses of monosaccharides" @default.
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