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- W1647115204 abstract "Laser magnetic resonance (LMR) spectroscopy, in which molecular transitions are Zeeman-shifted into coincidence with fixed laser frequencies, is now a well-established technique for studying unstable molecules. It was first developed in the far-infrared to study pure rotational spectra; progress in this region has been reviewed by EVENSON et al. [1]. More recently, LMR has been used in the mid-infrared region of CO (5–8 μm) and CO2 (9–11 μm) lasers to study vibration-rotation spectra; this has been reviewed by MCKELLAR [2]. Infrared-radiofrequency or -microwave double resonance [3] is another fruitful spectroscopic technique that utilizes mid-infrared lasers. This paper presents some results combining the double resonance and LMR techniques. Such a combination yields precise optically-detected EPR measurements within excited and ground vibrational levels, and can also serve as a useful aid for the assignment of difficult LMR spectra. Our technique is analogous to the combination of infrared-microwave double resonance and CO2 laser Stark spectroscopy used by TANAKA et al. [4], and of infrared-optical double resonance and CO2 LMR used by AMANO et al. [5]." @default.
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- W1647115204 date "1981-01-01" @default.
- W1647115204 modified "2023-09-24" @default.
- W1647115204 title "Laser Magnetic Double Resonance Spectra at 5 and 10μm" @default.
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- W1647115204 doi "https://doi.org/10.1007/978-3-540-38804-3_62" @default.
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