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• W1647362235 endingPage "330" @default.
• W1647362235 startingPage "291" @default.
• W1647362235 abstract "Publisher Summary This chapter describes the desorption phenomena, focusing on the rotational and translational motions of desorbed molecules. It describes desorption induced by electronic transitions (DIET) process stimulated by ultraviolet (UV) and visible nanosecond pulsed lasers for adsorbed diatomic molecules of nitrogen monoxide (NO) and carbon monoxide (CO) from surfaces. Non-thermal laser-induced desorption of NO and CO from metal surfaces occurs via two schemes of DIET and DIMET (desorption induced by multiple electronic transitions). DIET is induced by nanosecond-pulsed lasers and has been observed in the following systems: NO from platinum (Pt)(0 0 1), Pt(1 1 1), copper (1 1 1) and silver (Ag)(1 1 1), and CO from Pt(0 0 1) and Pt(1 1 1). On the other hand, these molecules are not desorbed from nickel (Ni) and palladium (Pd) metal surfaces in spite of the isoelectronic character of the metals Ni, Pd, and Pt. Desorption induced by subpicosecond-pulsed laser takes place via multiple correlated electronic transitions, DIMET. DIMET is a very different mechanism from DIET, and in DIMET, the vibrational excitation during the multiple electronic transitions leads to desorption. Desorption via multiple vibrational transitions is observed using an infrared laser. The chapter describes desorption processes undergoing a single excitation for NO and CO desorption from both metal and oxide surfaces." @default.
• W1647362235 created "2016-06-24" @default.
• W1647362235 creator A5015450627 @default.
• W1647362235 creator A5036715462 @default.
• W1647362235 date "2003-01-01" @default.
• W1647362235 modified "2023-10-18" @default.
• W1647362235 title "Laser-induced desorption from metal and oxide surfaces" @default.
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• W1647362235 doi "https://doi.org/10.1016/s1571-0785(03)11010-3" @default.
• W1647362235 hasPublicationYear "2003" @default.
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