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- W1649186148 abstract "We have investigated the structure, defect concentration, and superconducting properties of ${mathrm{HgBa}}_{2}$${mathrm{Ca}}_{2}$${mathrm{Cu}}_{3}$${mathrm{O}}_{8+mathrm{ensuremath{delta}}}$ by neutron powder diffraction, thermogravimetric analysis, and ac susceptibility. Samples with three oxygen contents and ${mathit{T}}_{mathit{c}}$'s ranging from 135 to 94 K, obtained through different annealing conditions, were studied. Two defect sites were observed in all samples. The concentration of defect oxygen atoms located at a site in the center of the Hg-${mathrm{O}}_{mathrm{ensuremath{delta}}}$ plane, is found to vary from 0.18(2) to 0.10(2) oxygen atoms per formula unit as ${mathit{T}}_{mathit{c}}$ decreases from 135 to 94 K. An additional defect, which we interpret as oxygen atoms associated with the substitution of Cu on the Hg site, is found to have a fixed concentration of ensuremath{sim}0.09(2) oxygen atoms per formula unit." @default.
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- W1649186148 date "1995-06-01" @default.
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- W1649186148 title "Structure and superconductivity of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>HgBa</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ca</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math…" @default.
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- W1649186148 doi "https://doi.org/10.1103/physrevb.51.15407" @default.
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