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- W1650230871 abstract "10% $^{13}mathrm{C}$ enriched ${mathrm{Rb}}_{4}$${mathrm{C}}_{60}$ was investigated by $^{13}mathrm{C}$ NMR. The relaxation rates ${mathit{T}}_{1}^{mathrm{ensuremath{-}}1}$ and ${mathit{T}}_{2}^{mathrm{ensuremath{-}}1}$ are basically determined by reorientation of the ${mathrm{C}}_{60}^{4mathrm{ensuremath{-}}}$ molecules. In addition, ${mathit{T}}_{1}^{mathrm{ensuremath{-}}1}$ exhibits an activated electronic contribution with activation energy 104 meV. The same activation energy is also found in Knight-shift measurements. Both compounds, ${mathrm{Rb}}_{4}$${mathrm{C}}_{60}$ and ${mathrm{K}}_{4}$${mathrm{C}}_{60}$, exhibit the same electronic excitation with the same activation energy within experimental error. We attribute this to a local excitation into a high-spin state of the Jahn-Teller distorted ${mathrm{C}}_{60}^{4mathrm{ensuremath{-}}}$." @default.
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- W1650230871 title "Rotational dynamics of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msubsup><mml:mrow><mml:mi mathvariant=normal>C</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mi mathvariant=normal>−</mml:mi></mml:mrow></mml:msubsup></mml:mrow></mml:math>and electronic excitation in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Rb</…" @default.
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- W1650230871 doi "https://doi.org/10.1103/physrevb.52.13300" @default.
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