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- W1650890882 abstract "The structural parameters of a nonsuperconductor (Pr 0.6 Sr 0.4 )(Pr 0.75 Ce 0.25 )CuO 4- z ( z =0.012) were refined by the Rietveld analysis of TOF neutron powder diffraction data. It is isomorphous with a superconductor (Nd 1- x Sr x )(Nd 1- y Ce y )CuO 4- z and consists of K 2 NiF 4 - and Nd 2 CuO 4 -type units stacked alternately along the c -axis. An apical oxygen site in the K 2 NiF 4 unit is 1.2% deficient. Pr atoms in the Nd 2 CuO 4 unit are, at least partially, in the oxidation state +4. The origin of nonsuperconductivity in this compound is discussed from a crystal chemical point of view." @default.
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- W1650890882 date "1990-10-01" @default.
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- W1650890882 title "Nonstoichiometry and Mixed Pr Valency in (Pr<sub>1-x</sub>Sr<sub>x</sub>)(Pr<sub>1-y</sub>Ce<sub>y</sub>)CuO<sub>4-z</sub>" @default.
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- W1650890882 doi "https://doi.org/10.1143/jjap.29.l1803" @default.
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